Croatia on Friday beat Brazil 4-2 to book a place in the semi final.
They will now meet the winner between Argentina and Holland in the semi final.
Brazil dominated the better part of the game, but it was as if the god of soccer was against them as the encounter ended 1-1 before the penalty shootout.
Brazil got eliminated from the World Cup after losing in the quarter-finals for the fourth time in the last five tournaments. Despite the pre-tournament as favorites, Brazil lost 4-2 in a penalty shootout to Croatia after it drew 1-1 draw in 120 minutes tension soaked encounter.